Method of presenting of results in qualitative analysis

Experiment

Observation

Conclusion

Put one spatula endful of the sample in a dry test tube and heat.

On gentle heating, water condensed on cooler parts of test tube a colour with pungent smell, was gas evolved. It turns red litmus blue and fumed HCI(g). Colourless gas with a chok adour evolved which turns blue decolourises potassium permanganate red-brown residue after heating.

+

Water of hydration from a hydrated salt, ammonia gas produced. NH4 present.

Put one spatula endful of the sample in a test tube and add water.

The solid dissolves forming a pale green solution.

Probably Fe2+, CU2+, Ni2+ present.

To the aqueous solution in a test tube add NaOH(aq) dropwise until in excess

Dirty green precipitate insoluble in excess, turns brown on exposure to air. On warming, a colour-less gas, with 000000a pungent smell was evolved, it turned red litmus blue and ..

+

 

Soluble compounds, probably soluble salt of Fe2+, and NH4 present

To 1cm3 of the solution in a test tube, add aqueous ammonia dropwise until in excess

Dirty green precipitate insoluble in excess, turned brown on exposure to air.

2-

Fe2+ present

To 1cm3 of the solution in a test tube, add dil. HNO33)2(aq) followed by Ba(NO

White precipitate, insoluble in the acid

2+

SO4

 

To 1cm3 of the test tube, add potassium

2-

hexacyanoferrate (III)

Dark blue precipitate

2-

Fe2+ confirmed present

To 1cm3 of the solution in the test tube, add AgNO3(aq)

White precipitate

2+

SO4  present

 

 

Identify the;

+

(a)  cations

       Fe2+  and NH4

2-

 

(b)   anion

2+

SO4

     Zn(OH)2(s)  + 4NH3(aq)            Zn(NH3) 4(aq) - 2OH-(aq)